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Statutory Instruments of the Scottish Parliament


You are here: BAILII >> Databases >> Statutory Instruments of the Scottish Parliament >> The Air Quality Standards (Scotland) Regulations 2007 No. 182
URL: http://www.bailii.org/scot/legis/num_reg/2007/20070182.html

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SCOTTISH STATUTORY INSTRUMENTS


2007 No. 182

ENVIRONMENTAL PROTECTION

The Air Quality Standards (Scotland) Regulations 2007

  Made 6th March 2007 
  Laid before the Scottish Parliament 7th March 2007 
  Coming into force 29th March 2007 


ARRANGEMENT OF REGULATIONS


PART 1

General
1. Citation, commencement and extent
2. Definitions
3. Designation of competent authority

PART 2

Group A and Group B pollutants and ozone

CHAPTER 1

Air Quality Standards
4. Preliminary and application
5. Zones and agglomerations
6. Air quality standards

CHAPTER 2

Attainment of air quality standards
7. General attainment measures
8. Improvement plans
9. Other improvement measures

CHAPTER 3

Maintenance of air quality standards and action plans
10. Maintenance of air quality standards
11. Action plans

CHAPTER 4

Assessment
12. Duty to assess air quality
13. Assessment methods
14. Fixed and combined measurement
15. Sampling points
16. Other assessment requirements

PART 3

Other pollutants and background monitoring
17. Measurement of PM2.5
18. Measurement of ozone precursor substances
19. Monitoring of polycyclic aromatic hydrocarbons
20. Background monitoring

PART 4

Public information and participation
21. General requirements
22. Information regarding zones
23. Information on concentrations
24. Information on breach of alert or information threshold
25. Information on breach of air quality standards
26. Ozone annual report
27. Information on action and improvement plans
28. Public participation in improvement plans

PART 5

Miscellaneous provisions
29. Collation of information etc
30. Revocations

  SCHEDULE 1 — Air quality standards
 PART 1 — Limit values for Group A pollutants
 PART 2 — Margins of tolerance for benzene and nitrogen dioxide
 PART 3 — Target values for Group B pollutants
 PART 4 — Target values and long-term objectives for ozone

  SCHEDULE 2 — Information to be included in an Improvement Plan

  SCHEDULE 3 — Alert and information thresholds
 PART 1 — Alert thresholds for nitrogen dioxide and sulphur dioxide
 PART 2 — Alert and information thresholds for ozone

  SCHEDULE 4 — Assessment thresholds
 PART 1 — Assessment thresholds for Group A pollutants
 PART 2 — Assessment thresholds for Group B pollutants
 PART 3 — Determination of representative concentrations

  SCHEDULE 5 — Minimum number of sampling points
 PART 1 — Group A pollutants: human health based limit values and alert thresholds
 PART 2 — Group A pollutants: limit values for the protection of ecosystems or vegetation
 PART 3 — Group B pollutants
 PART 4 — Ozone
 PART 5 — Ozone: minimum number of sampling points for fixed measurements for zones attaining the long-term objectives

  SCHEDULE 6 — Location of sampling points
 PART 1 — Macroscale siting for Group A pollutants
 PART 2 — Macroscale siting for Group B pollutants and polycyclic aromatic hydrocarbons
 PART 3 — Macroscale siting for ozone
 PART 4 — Microscale siting
 PART 5 — Documentation and review of site selection

  SCHEDULE 7 — Requirements for assessment methods other than fixed measurement
 PART 1 — Group A pollutants
 PART 2 — Group B pollutants
 PART 3 — Ozone and ozone precursor substances

  SCHEDULE 8 — Data quality objectives
 PART 1 — Group A pollutants and PM2.5
 PART 2 — Group B pollutants, polycyclic aromatic hydrocarbons and total gaseous mercury
 PART 3 — Ozone and related nitrogen oxide and nitrogen dioxide assessed at ozone sampling points

  SCHEDULE 9 — Reference methods
 PART 1 — Group A pollutants
 PART 2 — Group B pollutants in ambient air
 PART 3 — Ozone
 PART 4 — Other reference methods

  SCHEDULE 10 — Ozone precursor substances

  SCHEDULE 11 — Public information where alert or information thresholds are exceeded
 PART 1 — Alert thresholds for nitrogen dioxide and sulphur dioxide
 PART 2 — Alert and information thresholds for ozone

  SCHEDULE 12 — Collation of information and criteria for aggregating data and calculating statistical parameters
 PART 1 — Information to be submitted to the Commission
 PART 2 — Criteria for aggregating data and calculating statistical parameters

The Scottish Ministers, in exercise of the powers conferred by section 2(2) of the European Communities Act 1972[
1] and of all other powers enabling them in that behalf, hereby make the following Regulations:



PART 1

General

Citation, commencement and extent
     1. —(1) These Regulations may be cited as the Air Quality Standards (Scotland) Regulations 2007 and shall come into force on 29th March 2007.

    (2) These Regulations extend to Scotland only.

Definitions
    
2. —(1) In these Regulations–

and, in both cases, a reference to a concentration is to a concentration assessed by the Scottish Ministers in accordance with these Regulations;

    (2) Subject to paragraph 1 words and expressions used both in these Regulations and in the following Directives shall have the same meaning in these Regulations as in the relevant Directive–

Designation of competent authority
     3. The Scottish Ministers are designated as the competent authority for the purposes of Article 3 (implementation and responsibilities) of Council Directive 96/62/EC on ambient air quality assessment and management.



PART 2

Group A and Group B pollutants and ozone



CHAPTER 1

Air Quality Standards

Preliminary and application
    
4. —(1) This Part applies in respect of the following pollutants:–

    (2) The Scottish Ministers shall ensure that all measures taken under Chapters 2 or 3 of this Part–

Zones and agglomerations
    
5. —(1) The Scottish Ministers shall, for the purposes of this Part, divide the territory of Scotland into zones.

    (2) A zone shall be classified as an agglomeration for the purposes of this Part where–

    (3) The Scottish Ministers may establish different zones for different pollutants where they consider this appropriate.

Air quality standards
    
6. —(1) Schedule 1 prescribes the following air quality standards–

    (2) Limit values–

    (3) Target values shall be attained from the attainment date specified, in so far as this is possible through measures required by regulation 7.

    (4) In the case of benzene and nitrogen dioxide, the margins of tolerance set out in Part 2 of Schedule 1 apply within the periods specified.



CHAPTER 2

Attainment of air quality standards

General attainment measures
    
7. —(1) The Scottish Ministers shall take the necessary measures to ensure that the air quality standards set out in regulation 6 are attained.

    (2) In the case of Group B pollutants, the necessary measures are–

    (3) In the case of ozone, the necessary measures are measures the Scottish Ministers consider to be proportionate and, in relation to the long term objectives, cost effective.

Improvement plans
     8. —(1) This regulation applies in respect of each zone in which prior to the attainment date–

    (2) Where paragraph (1)(a) applies, the Scottish Ministers shall prepare and implement an improvement plan for the pollutant in question or, where concentrations of both pollutants exceed the level referred to, a single improvement plan for both pollutants.

    (3) Where paragraph (1)(b) applies, the Scottish Ministers shall prepare and implement an improvement plan in respect of ozone unless they consider that the target value would not be attainable through proportionate measures.

    (4) An improvement plan shall include the information specified in Schedule 2.

    (5) Where the Scottish Ministers are required to prepare and implement an improvement plan under both paragraphs (2) and (3), they shall, where they consider it appropriate, prepare and implement an integrated improvement plan covering all of the pollutants concerned.

    (6) An improvement plan may comprise either a plan or a programme which, in either case, shall have the objective of attaining–

Other improvement measures
    
9. —(1) This regulation applies in respect of each zone in which–

    (2) Where paragraph (1)(a) applies, the Scottish Ministers shall–

    (3) Where paragraph (1)(b) applies, the Scottish Ministers shall prepare and implement measures which they consider to be cost-effective with the aim of attaining the long-term objective.

    (4) The Scottish Ministers shall ensure that the measures required in paragraph (3) are consistent with the improvement plans prepared for ozone under regulation 8(3).



CHAPTER 3

Maintenance of air quality standards and action plans

Maintenance of air quality standards
    
10. —(1) This regulation applies in respect of each zone in which–

    (2) Where sub-paragraphs (a) or (b) of paragraph (1) apply, the Scottish Ministers shall, in respect of each pollutant meeting the conditions set out in those sub paragraphs–

    (3) Where paragraph (1)(c) applies, the Scottish Ministers shall–

Action plans
    
11. —(1) The Scottish Ministers shall–

action plans.

    (2) The action plans shall indicate the measures to be taken within any zone in the short term in order to achieve the objectives set out in paragraph (3) in the event of circumstances in which the Scottish Ministers consider there is a risk that any one of the following will be exceeded:–

    (3) The objectives of each action plan shall be–

    (4) In relation to ozone, the obligation imposed by paragraph (1)(a) shall only apply in so far as, taking into account geographical, meteorological and economic conditions, the Scottish Ministers consider there is significant potential for the objectives set out in paragraph (3) to be achieved.

    (5) When the Scottish Ministers consider that the risks referred to in paragraph (2) arise within a zone, they shall implement the measures indicated in the relevant action plans within that zone to the extent they consider necessary in the circumstances.

    (6) In preparing and implementing any action plans for ozone, the Scottish Ministers shall have regard to Annexes I and II to Commission Decision 2004/279/EC concerning guidance for implementation of Directive 2002/3/EC[
10].

    (7) Schedule 3 has effect in prescribing–



CHAPTER 4

Assessment

Duty to assess air quality
     12. The Scottish Ministers shall assess the concentration of each pollutant within each zone in accordance with regulations 13 to 16.

Assessment methods
    
13. —(1) Subject to paragraph (2), the Scottish Ministers shall assess concentrations of a Group A pollutant by fixed measurement where–

    (2) Where the zone concerned is the same as that established under the Air Quality Limit Values (Scotland) Regulations 2003[11] ("the 2003 Regulations"), the Scottish Ministers may continue to use the method by which concentrations of a Group A pollutant were assessed within that zone under the 2003 Regulations ("the 2003 method").

    (3) Except where fixed measurement is required by paragraph (1) or they continue to use the 2003 method in accordance with paragraph (2), and, in the case of nitrogen dioxide, subject to the requirements imposed by regulation 15(7), the Scottish Ministers may assess concentrations of a Group A pollutant by any one of the following methods–

    (4) The Scottish Ministers shall assess concentrations of a Group B pollutant by fixed measurement in any zone in which representative concentrations of that pollutant exceed the relevant upper assessment threshold.

    (5) Except where fixed measurement is required by paragraph (4), the Scottish Ministers may assess concentrations of a Group B pollutant by one of the following methods:–

    (6) For the purposes of paragraphs (1) and (3) to (5), the Scottish Ministers shall determine the representative concentrations in accordance with Part 3 of Schedule 4.

    (7) The Scottish Ministers shall review the method by which concentrations of a Group A or Group B pollutant are assessed at least once every five years or earlier if there are significant changes in activities affecting concentrations of the relevant pollutant within the zone concerned.

    (8) Where the Scottish Ministers continue to use the 2003 method, the date from which the period of review commences is the later of–

    (9) The Scottish Ministers shall assess concentrations of ozone by fixed measurement if, within the zone concerned, concentrations have exceeded a long-term objective during any of the previous five years of measurement.

    (10) In cases where fewer than five years' information on concentrations is available, the Scottish Ministers may assess concentrations of ozone by combining the following:–

Fixed and combined measurement
     14. —(1) Where the Scottish Ministers assess concentrations of a Group A or Group B pollutant by fixed measurement, whether alone or as part of combined measurement, they shall ensure that–

    (2) Where the Scottish Ministers assess concentrations of a Group A or Group B pollutant by fixed measurement, they may supplement information from sampling points for fixed measurement with information from modelling techniques in so far as they consider this will provide an adequate level of information on ambient air quality.

    (3) Where the Scottish Ministers assess concentrations of ozone by fixed measurement–

Sampling points
    
15. —(1) Where the Scottish Ministers assess concentrations of a Group A or Group B pollutant by fixed measurement they shall, except in cases falling within paragraph (2)(a), install the number of sampling points required for the zone in accordance with the relevant Part of Schedule 5.

    (2) Where the Scottish Ministers assess concentrations of a Group A or Group B pollutant by–

they shall install the number of sampling points they determine is sufficient, taken together with the spatial resolution of the other techniques employed, for concentrations of the relevant pollutant to be established within the zone concerned.

    (3) The Scottish Ministers shall locate all sampling points for Group A and Group B pollutants in accordance with the requirements set out in the relevant Parts of Schedule 6.

    (4) Where the Scottish Ministers assess concentrations of ozone by fixed measurement they shall, except where paragraphs (5) or (6) apply, install the number of sampling points required for the zone in accordance with Part 4 of Schedule 5.

    (5) In the case of zones where–

the Scottish Ministers may determine the number of sampling points in accordance with Part 5 of Schedule 5.

    (6) In the case of zones in which the Scottish Ministers supplement the information obtained from sampling points for fixed measurement with information from modelling techniques or indicative measurement in accordance with regulation 14(3)(b), they may reduce the number of sampling points for ozone provided that–

    (7) The Scottish Ministers shall ensure that–

    (8) The Scottish Ministers shall locate all sampling points for ozone in accordance with the requirements set out in the relevant Parts of Schedule 6.

Other assessment requirements
    
16. —(1) When the Scottish Ministers undertake assessments by methods other than fixed measurement, they shall comply with the requirements of the relevant Part of Schedule 7 when using those other methods.

    (2) When conducting any assessment under this Chapter, the Scottish Ministers shall have regard to the relevant data quality objectives set out in Schedule 8.

    (3) The Scottish Ministers shall undertake assessments in accordance with–

    (4) Measurements of volume of benzene, carbon monoxide, nitrogen dioxide, oxides of nitrogen, ozone and sulphur dioxide shall be standardised at a temperature of 293K and a pressure of 101.3 kPa.



PART 3

Other pollutants and background monitoring

Measurement of PM2.5
    
17. —(1) The Scottish Ministers shall install and operate measuring stations to supply representative data on concentrations of PM2.5.

    (2) For the purpose of paragraph (1), the Scottish Ministers shall–

Measurement of ozone precursor substances
    
18. —(1) The Scottish Ministers shall install and operate one or, if they consider it necessary, more measuring stations to supply data on concentrations of the ozone precursor substances set out in Schedule 10.

    (2) When complying with paragraph (1) the Scottish Ministers shall have regard–

Monitoring of polycyclic aromatic hydrocarbons
    
19. —(1) The Scottish Ministers shall monitor concentrations of–

at monitoring sites designated by them for this purpose.

    (2) The Scottish Ministers shall locate each monitoring site–

    (3) The total number of monitoring sites and their overall selection shall be such as the Scottish Ministers consider necessary to ensure that the monitoring provides sufficient information to identify long-term trends and geographical variation in the concentration of each polycyclic aromatic hydrocarbon.

    (4) Regulation 16(2) and (3) shall apply to the monitoring required by this regulation as if such monitoring were an assessment under Chapter 4 of Part 2.

Background monitoring
    
20. —(1) The Scottish Ministers shall install and operate background sampling points to provide the measurements required by paragraph (2).

    (2) The measurements required are indicative measurements of–

    (3) For the purposes of paragraphs (1) and (2), the Scottish Ministers shall ensure that–

    (4) Regulation 16(2) and (3) shall apply to the taking of measurements referred to in paragraph (2) as if the taking of these measurements were an assessment under Chapter 4 of Part 2.

    (5) The Scottish Ministers may–

    (6) For the purpose of paragraph (2)(a)(iii), "total gaseous mercury" means–



PART 4

Public information and participation

General requirements
     21. —(1) The Scottish Ministers shall–

    (2) The Scottish Ministers shall ensure that the information to which this Part relates is–

    (3) For the purposes of this Part, "the public" includes natural or legal persons, health-care bodies and other organisations having an interest in ambient air quality or representing the interests of sensitive populations, consumers or the environment.

Information regarding zones
    
22. The Scottish Ministers shall make available–

Information on concentrations
    
23. —(1) The Scottish Ministers shall make available information in respect of–

    (2) The information referred to in paragraph (1)(a) shall be updated in the case of–

    (3) The information required to be made available by paragraph (1)(c) shall be updated–

    (4) The information required to be made available by paragraph (1)(d)(i) in respect of PM2.5 shall be updated at least on a daily basis.

Information on breach of alert or information threshold
    
24. —(1) The Scottish Ministers shall, as soon as possible in each case, make available–

    (2) In cases where the Scottish Ministers make information available under both sub paragraphs (a) and (b) of paragraph (1) they shall combine the information in a comprehensive format.

    (3) Without prejudice to the generality of the obligation imposed by this regulation in cases where the alert threshold for ozone is exceeded, or is predicted to be exceeded, the Scottish Ministers shall ensure that timely information is provided to health care bodies.

Information on breach of air quality standards
    
25. —(1) The Scottish Ministers shall provide the information required by paragraphs (2) to (5) in respect of each of the pollutants to which those paragraphs relate.

    (2) For Group A pollutants, the Scottish Ministers shall indicate the extent to which the following have been exceeded:–

and provide a short assessment of these occurrences and their effects on health.

    (3) For Group B pollutants, the Scottish Ministers shall–

    (4) For ozone, the Scottish Ministers shall–

    (5) The Scottish Ministers shall update the information referred to in paragraphs (2) and (4) in accordance with the timescales specified for the pollutants in question by regulation 23(2) and (3).

Ozone annual report
    
26. —(1) The Scottish Ministers shall produce an annual report in relation to ozone containing the following information:–

    (2) The information referred to in paragraph (1) may include, where appropriate–

Information on action and improvement plans
    
27. —(1) The Scottish Ministers shall make available, and provide information on the implementation of, each action plan and improvement plan.

    (2) Where regulation 11(4) applies, the Scottish Ministers shall make available the results of the investigations undertaken in the context of their considerations under that regulation, irrespective of whether they have prepared an action plan under regulation 11(1)(a).

Public participation in improvement plans
    
28. —(1) The Scottish Ministers shall consult the public where they propose to prepare, modify or review an improvement plan.

    (2) Where paragraph (1) applies, the Scottish Ministers shall–

    (3) Where, following a consultation, the Scottish Ministers take a decision in relation to their proposal, they shall inform the public and provide information as to the reasons and considerations on which their decision is based as well as information as to the public participation process.



PART 5

Miscellaneous provisions

Collation of information etc
    
29. —(1) The Scottish Ministers shall ensure that the information specified in Part 1 of Schedule 12 is obtained and collated.

    (2) The criteria for aggregating data and calculating statistical parameters specified in Part 2 of Schedule 12 shall apply in the case of ozone.

Revocations
    
30. —(1) Subject to regulation 13(2), the following Regulations are revoked:–

    (2) The following regulations are revoked with effect from, and including, 1st January 2010[16]:–


SARAH H BOYACK
Authorised to sign by the Scottish Ministers

St Andrew's House, Edinburgh
6th March 2007



SCHEDULE 1
Regulation 6


Air quality standards




PART 1

Limit values for Group A pollutants

Benzene


           Averaging period Limit value Attainment date
Limit value for the protection of human health Calendar year 5 µg/m³ 1st January 2010

Carbon monoxide
For the purposes of this table, the maximum daily 8-hour mean concentration shall be selected by examining 8-hour running averages, calculated from hourly data and updated each hour. Each 8 hour average so calculated shall be assigned to the day on which it ends, i.e. the first calculation period for any one day shall be the period from 17:00 on the previous day to 01:00 on that day; the last calculation period for any one day shall be the period from 16:00 to 24:00 on that day.

           Averaging period Limit value
Limit value for the protection of human health Maximum daily 8-hour mean 10 mg/m³

Lead
           Averaging period Limit value
Annual limit value for the protection of human health Calendar year 0.5 µg/m³

Nitrogen dioxide (NO2) and oxides of nitrogen (NOx)
           Averaging period Limit value Attainment date
Hourly limit value for the protection of human health 1 hour 200 µg/m³ NO2, not to be exceeded more than 18 times a calendar year 1st January 2010
Annual limit value for the protection of human health Calendar year 40 µg/m³ NO2 1st January 2010
Annual limit value for the protection of vegetation Calendar year 30 µg/m³ NOx           

PM10
           Averaging period Limit value
24-hour limit value for the protection of human health 24 hours 50 µg/m³ PM10, not to be exceeded more than 35 times a calendar year
Annual limit value for the protection of human health Calendar year 40 µg/m³ PM10

Sulphur dioxide
           Averaging period Limit value
Hourly limit value for the protection of human health 1 hour 350 µg/m³, not to be exceeded more than 24 times a calendar year
Daily limit value for the protection of human health 24 hours 125 µg/m³, not to be exceeded more than 3 times a calendar year
Limit value for the protection of ecosystems Calendar year and winter (1st October to 31st March) 20 µg/m³



PART 2

Margins of tolerance for benzene and nitrogen dioxide

Start of period during which the margin applies End of period during which the margin applies Benzene Nitrogen dioxide (hourly limit value for the protection of human health) Nitrogen dioxide (annual limit value for the protection of human health)
Coming into force of these Regulations 31st December 2007 3 µg/m³ 30 µg/m³ 6 µg/m³
1st January 2008 31st December 2008 2 µg/m³ 20 µg/m³ 4 µg/m³
1st January 2009 31st December 2009 1 µg/m³ 10 µg/m³ 2 µg/m³



PART 3

Target values for Group B pollutants

     1. The target values in the table at paragraph 2 in each case relate to the total content of the relevant pollutant in the PM10 fraction averaged over one calendar year.

     2. The attainment date for each of these target values is 31st December 2012.

Pollutant Target value
Arsenic 6 ng/m³
Benzo(a)pyrene 1 ng/m³
Cadmium 5 ng/m³
Nickel 20 ng/m³



PART 4

Target values and long-term objectives for ozone

     3. In this Part–

Target values
The attainment date for the target values set out in the following table is 2010, with compliance assessed over the periods indicated for each target value in the table.

           Parameter Target value and assessment for 2010(¹)
Target value for the protection of human health Maximum daily 8-hour mean(²) 120 µg/m³ not to be exceeded on more than 25 days per calendar year averaged over three years(³)
Target value for the protection of vegetation AOT 40, calculated from 1 hour values from May to July 18,000 µg/m³.hour averaged over five years(³)

(¹) Compliance with target values will be assessed as of this value. That is, 2010 will be the first year the data for which is used in calculating compliance over three or five years, as appropriate.

(²) The maximum daily 8-hour mean concentration shall be selected by examining 8-hour running averages, calculated from hourly data and updated each hour. Each 8-hour average so calculated shall be assigned to the day on which it ends, that is, the first calculation period for any one day shall be the period from 17:00 on the previous day to 01:00 on that day; the last calculation period for any one day will be the period from 16:00 to 24:00 on the day.

(³) If the three or five year averages cannot be determined on the basis of a full and consecutive set of annual data, the minimum annual data required for checking compliance with the target values shall be as follows: (i) for the target value for the protection of human health, valid data for one year; and (ii) for the target value for the protection of vegetation, valid data for three years.

Long-term objectives


           Parameter Long-term objective
Long-term objective for the protection of human health Maximum daily 8-hour mean within a calendar year 120 µg/m³
Long-term objective for the protection of vegetation AOT40, calculated from 1 h values from May to July 6,000 µg/m³.h



SCHEDULE 2
Regulation 8(4)


Information to be included in an Improvement Plan


     1. Localisation of excess pollution–

     2. General information–

     3. Responsible authorities (names and addresses of persons responsible for the development and implementation of improvement plans).

     4. Nature and assessment of pollution–

     5. Origin of pollution–

     6. Analysis of the situation–

     7. Details of those measures or projects for improvements which existed prior to 21st November 1996–

     8. Details of those measures or projects adopted with a view to reducing pollution following 21st November 1996–

     9. Details of the measures or projects planned or being researched for the long term.

     10. List of the publications, documents, and work used to supplement information required by this Schedule.



SCHEDULE 3
Regulation 11(7)


Alert and information thresholds




PART 1

Alert thresholds for nitrogen dioxide and sulphur dioxide

Nitrogen dioxide 400 µg/m³ measured over three consecutive hours at locations representative of air quality over at least 100 km² or an entire zone or agglomeration, whichever is the smaller
Sulphur dioxide 500 µg/m³ measured over three consecutive hours at locations representative of air quality over at least 100 km² or an entire zone or agglomeration, whichever is the smaller



PART 2

Alert and information thresholds for ozone

           Parameter Threshold
Alert threshold 1 hour average(¹) 240 µg/m³
Information threshold 1 hour average 180 µg/m³

(¹) For the purposes of regulation 11 (action plans), exceedance of the 1 hour average in respect of the alert threshold is to be measured or predicted for three consecutive hours.



SCHEDULE 4
Regulation 2(1) Regulation 13(6)


Assessment thresholds




PART 1

Assessment thresholds for Group A pollutants

Benzene


           Annual average
Upper assessment threshold 70% of limit value (3.5 µg/m³)
Lower assessment threshold 40% of limit value (2 µg/m³)

Carbon monoxide


           Eight-hour average
Upper assessment threshold 70% of limit value (7 mg/m³)
Lower assessment threshold 50% of limit value (5 mg/m³)

Lead


           Annual average
Upper assessment threshold 70% of limit value (0.35 µg/m³)
Lower assessment threshold 50% of limit value (0.25 µg/m³)

Nitrogen dioxide (NO2) and oxides of nitrogen (NOx)


           Hourly limit value for the protection of human health (NO2 ) Annual limit value for the protection of human health (NO2) Annual limit value for the protection of vegetation (NOx)
Upper assessment threshold 70% of limit value (140 µg/m³), not to be exceeded more than 18 times in any calendar year 80% of limit value (32 µg/m³) 80% of limit value (24 µg/m³)
Lower assessment threshold 50% of limit value (100 µg/m³), not to be exceeded more than 18 times in any calendar year 65% of limit value (26 µg/m³) 65% of limit value (19.5 µg/m³)

PM10


           24-hour average Annual average
Upper assessment threshold 60% of limit value (30 µg/m³), not to be exceeded more than 7 times in any calendar year 70% of limit value (14 µg/m³)
Lower assessment threshold 40% of limit value (20 µg/m³), not to be exceeded more than 7 times in any calendar year 50% of limit value (10 µg/m³)

Sulphur dioxide


           Health protection Ecosystem protection
Upper assessment threshold 60% of 24-hour limit value (75 µg/m³), not to be exceeded more than 3 times in any calendar year 60% of winter limit value (12 µg/m³)
Lower assessment threshold 40% of 24-hour limit value (50 µg/m³), not to be exceeded more than 3 times in any calendar year 40% of winter limit value (8 µg/m³)



PART 2

Assessment thresholds for Group B pollutants

Arsenic


Upper assessment threshold 60% of target value (3.6 ng/m³)
Lower assessment threshold 40% of target value (2.4 ng/m³)

Benzo(a)pyrene


Upper assessment threshold 60% of target value (0.6 ng/m³)
Lower assessment threshold 40% of target value (0.4 ng/m³)

Cadmium


Upper assessment threshold 60% of target value (3 ng/m³)
Lower assessment threshold 40% of target value (2 ng/m³)

Nickel


Upper assessment threshold 70% of target value (14 ng/m³)
Lower assessment threshold 50% of target value (10 ng/m³)



PART 3

Determination of representative concentrations

     1. The representative concentration of the relevant pollutant shall be determined on the basis of concentrations during the previous five years where sufficient data are available. The upper assessment threshold will be deemed to have been exceeded if it has been exceeded during at least three separate years out of the previous five years. The lower assessment threshold will be deemed to have been equalled or exceeded if it has been equalled or exceeded during at least three separate years out of the previous five years.

     2. Where fewer than five years' data are available, measurement campaigns of short duration during the period of the year and at locations likely to be typical of the highest concentrations may be combined with results obtained from emission inventories and modelling to determine exceedances of the upper and lower assessment thresholds.



SCHEDULE 5
Regulation 15(1), (4), (5) and (7)


Minimum number of sampling points




PART 1

Group A pollutants: human health based limit values and alert thresholds

     1. This Part sets out the minimum number of sampling points for fixed measurement of Group A pollutants to assess compliance with limit values for the protection of human health and alert thresholds in zones where fixed measurement is the sole source of information.

Diffuse sources


Population of zone (thousands) If concentrations exceed the upper assessment threshold(¹) If maximum concentrations are between the upper and lower assessment thresholds For nitrogen dioxide and sulphur dioxide in agglomerations where maximum concentrations are below the lower assessment thresholds
0–249 1 1 not applicable
250–499 2 1 1
500–749 2 1 1
750–999 3 1 1
1,000–1,499 4 2 1
1,500–1,999 5 2 1
2,000–2,749 6 3 2
2,750–3,749 7 3 2
3,750–4,749 8 4 2
4,750–5,999 9 4 2
6,000 or more 10 5 3

(¹) For NO2 and PM10 to include at least one urban-background station and one traffic-orientated station; this requirement shall also apply to benzene and carbon monoxide provided that it does not increase the number of sampling points.

Point sources
     2. For the assessment of pollution in the vicinity of point sources, the number of sampling points for fixed measurement shall be calculated taking into account emission densities, the likely distribution patterns of ambient-air pollution and the potential exposure of the population.



PART 2

Group A pollutants: limit values for the protection of ecosystems or vegetation

     3. The following table sets out the minimum number of sampling points for fixed measurements to assess compliance with limit values for the protection of ecosystems or vegetation in zones other than agglomerations.

If maximum concentrations exceed the upper assessment threshold If maximum concentrations are between the upper and lower assessment thresholds
1 station every 20,000 km² 1 station every 40,000 km²

     4. In island zones the number of sampling points for fixed measurement shall be calculated taking into account the likely distribution patterns of ambient-air pollution and the potential exposure of ecosystems or vegetation.



PART 3

Group B pollutants

     5. This Part sets out the minimum number of sampling points for fixed measurement of Group B pollutants to assess compliance with target values for the protection of human health in zones where fixed measurement is the sole source of information.

Diffuse sources


Population of zone (thousands) If maximum concentrations exceed the upper assessment threshold(¹) If maximum concentrations are between the upper and lower assessment thresholds
           Arsenic, Cadmium, Nickel Benzo(a)pyrene Arsenic, Cadmium, Nickel Benzo(a)pyrene
0–749 1 1 1 1
750–1999 2 2 1 1
2000–3749 2 3 1 1
3750–4749 3 4 2 2
4750–5999 4 5 2 2
≥6000 5 5 2 2

(¹) To include at least one urban-background station and for benzo(a)pyrene also one traffic-oriented station provided this does not increase the number of sampling points.

Point sources
     6. For the assessment of pollution in the vicinity of point sources, the number of sampling points for fixed measurement shall be determined taking into account emission densities, the likely distribution patterns of ambient air pollution and potential exposure of the population. The sampling points should shall be sited such that the application of the measures referred to at regulation 7(2)(b) can be monitored.



PART 4

Ozone

     7. Except in so far as otherwise provided by regulation 15(5) or (6), the minimum number of sampling points for fixed continuous measurement to assess air quality in view of compliance with the target values, long-term objectives and information and alert thresholds where continuous measurement is the sole source of information is set out in the following table below.

Population of zone (thousands) Agglomerations (urban and suburban)(¹) Other zones (suburban and rural)(¹) Rural background
0–249 1 1 1 station/50,000 km² as an average density over all zones in Scotland(²)
250–499 1 2           
500–999 2 2           
1,000–1,499 3 3           
1,500–1,999 3 4           
2,000–2,749 4 5           
2,750–3,749 5 6           
3,750 or more 1 additional station per 2 million inhabitants 1 additional station per 2 million inhabitants           

(¹) At least 1 station in suburban areas, where the highest exposure of the population is likely to occur. In agglomerations at least 50% of the stations should shall be located in suburban areas.

(²) 1 station per 25,000 km² for complex terrain is recommended.



PART 5

Ozone: minimum number of sampling points for fixed measurements for zones attaining the long-term objectives

     8. In cases where zones attain the long-term objectives, the number of sampling points for ozone shall, in combination with other means of supplementary assessment such as air quality modelling and co-located nitrogen dioxide measurements, be sufficient to examine the trend of ozone pollution and check compliance with the long-term objectives.

     9. The number of stations located in agglomerations and other zones may be reduced to one third of the number specified in the Table in Part 4 of this schedule. Where information from fixed measurement stations is the sole source of information, at least one monitoring station shall be kept. If, in zones where there is supplementary assessment, the result of this is that a zone has no remaining station, co-ordination with the number of stations in neighbouring zones must ensure adequate assessment of ozone concentrations against long-term objectives.

     10. The number of rural background stations should shall be 1 per 100,000 km².



SCHEDULE 6
Regulation 15(3) and (8) Regulation 17(2)(b)(ii) Regulation 19(2)(b) Regulation 20(3)(b)


Location of sampling points




PART 1

Macroscale siting for Group A pollutants

Sampling points for the protection of human health
     1. Sampling points directed at the protection of human health shall be sited to provide data on:–

     2. Sampling points shall in general be sited to avoid measuring very small micro-environments in their immediate vicinity. Where possible, the Scottish Ministers shall locate sampling points so as to be representative of air quality in a surrounding area of no less than 200 m² at traffic-orientated sites and of several square kilometres at urban-background sites.

     3. Sampling points shall also, where possible, be representative of similar locations not in their immediate vicinity.

     4. Account shall be taken of the need to locate sampling points on islands, where that is necessary for the protection of human health.

Protection of ecosystems and vegetation
     5. Sampling points targeted at the protection of ecosystems or vegetation shall be sited more than 20 km from agglomerations or more than 5 km from other built-up areas, industrial installations or motorways. Where possible, the Scottish Ministers shall locate sampling points so as to be representative of air quality in a surrounding area of at least 1000 km². A sampling point may be sited at a lesser distance or to be representative of air quality in a less extended area, taking account of geographical conditions. Account shall be taken of the need to assess air quality on islands.



PART 2

Macroscale siting for Group B pollutants and polycyclic aromatic hydrocarbons

     6. The sites of sampling points shall be selected in such a way as to provide data on–

     7. Sampling points shall in general be sited so as to avoid measuring very small micro-environments in their immediate vicinity. Where possible, the Scottish Ministers shall locate sampling points so as to be representative of air quality in surrounding areas of no less than 200 m² at traffic-orientated sites, at least 250 m × 250 m at industrial sites, where feasible, and several square kilometres at urban-background sites.

     8. Where the objective is to assess background levels the sampling site shall not be influenced by agglomerations or industrial sites in its vicinity, i.e. sites closer than a few kilometres (as the Scottish Ministers may determine in light of the circumstances of each case).

     9. Where contributions from industrial sources are to be assessed, at least one sampling point shall be installed downwind of the source in the nearest residential area. Where the background concentration is not known, an additional sampling point shall be situated within the main wind direction. In particular in cases falling within regulation 9(1)(a), the sampling points shall be sited such that the application of the measures referred to at regulation 7(2)(b) can be monitored.

     10. Sampling points shall also, where possible, be representative of similar locations not in their immediate vicinity. Where appropriate they shall be co-located with sampling points for PM10.



PART 3

Macroscale siting for ozone

     11. Sampling points for ozone shall be located in accordance with the considerations set out in the following table–

Type of station Objective of measurement Representativeness(¹) Macroscale siting criteria
Urban Protection of human health: to assess the exposure of the urban population to ozone, i.e. where the population density and ozone concentration are relatively high and representative of the exposure of the general population A few km² Away from the influence of local emissions such as traffic, petrol stations etc.; vented locations where well mixed levels can be measured; locations such as residential and commercial areas of cities, parks (away from the trees), big streets or squares with very little or no traffic open areas characteristic of education, sports or recreation facilities
Suburban Protection of human health and vegetation: to assess the exposure of the population and vegetation located in the outskirts of the agglomeration, where the highest ozone levels, to which the population and vegetation is likely to be directly or indirectly exposed, occur Some tens of km² At a certain distance from the area of maximum emissions, downwind following the main wind direction during conditions favourable to ozone formation; where population, sensitive crops or natural ecosystems located in the outer fringe of an agglomeration are exposed to high ozone levels; where appropriate, some sub urban stations also upwind of the area of maximum emissions, in order to determine the regional background levels of ozone
Rural Protection of human health and vegetation: to assess the exposure of population, crops and natural ecosystems to sub-regional scale ozone concentrations Sub-regional levels (a few km²) Stations can be located in small settlements and/or areas with natural ecosystems, forests or crops; representative for ozone away from the influence of immediate local emissions such as industrial installations and roads; at open area sites, but not on higher mountain-tops
Rural background Protection of vegetation and human health: to assess the exposure of crops and natural ecosystems to regional-scale ozone concentrations as well as exposure of the populations Regional/national/continental levels (1,000 to 10,000 km²) Station located in areas with lower population density, e.g. with natural ecosystems, forests, far removed from urban and industrial areas and away from local emissions; avoid locations which are subject to locally enhanced formation of near ground inversion conditions, also summits of higher mountains; coastal sites with pronounced diurnal wind cycles of local character are not recommended by Directive 2002/3/EC

(¹) Sampling points shall also, where possible, be representative of similar locations not in their immediate vicinity.

     12. For rural and rural background stations, consideration shall be given, where appropriate, to co ordination with the monitoring requirements of Commission Regulation 1091/94[
19] concerning protection of the Community's forests against atmospheric pollution.



PART 4

Microscale siting

     13. The following guidelines shall be met as far as practicable–

     14. The following factors may also be taken into account–



PART 5

Documentation and review of site selection

     15. The site-selection procedures shall be fully documented at the classification stage by such means as compass-point photographs of the surrounding area and a detailed map. Sites shall be reviewed at regular intervals with repeated documentation to ensure that selection criteria remain valid over time.

     16. For ozone, this requires screening and interpretation of the monitoring data in the context of the meteorological and photochemical processes affecting the ozone concentrations measured at the respective site.



SCHEDULE 7
Regulation 15(6)(b) Regulation 16(1)


Requirements for assessment methods other than fixed measurement




PART 1

Group A pollutants

     1. The following information shall be compiled for zones within which sources other than fixed measurement are employed to supplement information from fixed measurement or as the sole means of air quality assessment–

     2. Where possible maps shall be compiled showing concentration distributions within each zone.



PART 2

Group B pollutants

Requirements for air quality models
     3. Where an air quality model is used for assessment, references to descriptions of the model and information on the uncertainty shall be compiled. The uncertainty for modelling is defined as the maximum deviation of the measured and calculated concentration levels, over a full year, without taking into account the timing of the events.

Requirements for objective estimation techniques
     4. Where objective estimation techniques are used, the uncertainty shall not exceed 100% .

Standardisation
     5. For substances to be analysed in the PM10 fraction, the sampling volume shall refer to ambient conditions.



PART 3

Ozone and ozone precursor substances

     6. The following information shall be compiled for zones within which sources other than fixed measurement are employed to supplement information from measurement–

     7. The Scottish Ministers shall ensure that maps are compiled showing concentration distributions within each zone.



SCHEDULE 8
Regulation 16(2) Regulation 17(2)(d) Regulation 19(4) Regulation 20(4)


Data quality objectives




PART 1

Group A pollutants and PM2.5

Group A pollutants (other than benzene and carbon monoxide) and PM2.5
     1. The data-quality objectives set out in the following table for the required uncertainty of assessment methods, of minimum time coverage and of data capture of measurement are laid down to guide quality assurance programmes–

           Sulphur dioxide, nitrogen dioxide and oxides of nitrogen Lead, PM2.5 and PM10
Continuous measurement                      
Uncertainty 15% 25%
Minimum data capture 90% 90%
Indicative measurement                      
Uncertainty 25% 50%
Minimum data capture 90% 90%
Minimum time coverage 14% (One measurement a week at random, evenly distributed over the year, or eight weeks evenly distributed over the year) 14% (One measurement a week at random, evenly distributed over the year, or eight weeks evenly distributed over the year)
Modelling                      
Uncertainty                      
Hourly averages 50% –60%           
Daily averages 50%           
Annual averages 30% 50%
Objective estimation                      
Uncertainty 75% 100%

     2. The uncertainty of the measurement is defined as that set out in the "Guide to the Expression of Uncertainty of Measurements" (ISO 1993)[
20] or in ISO 5725-1 "Accuracy (trueness and precision) of measurement methods and results" (ISO 1994). The percentages in the table at paragraph 1 are given for individual measurements averaged, over the period considered, by the limit value, for a 95% confidence interval (bias + two times the standard deviation). The uncertainty for continuous measurements shall be interpreted as being applicable in the region of the appropriate limit value.

     3. The uncertainty for modelling and objective estimation is defined as the maximum deviation of the measured and calculated concentration levels, over the period considered by the limit value, without taking account the timing of the events.

     4. The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration or the normal maintenance of the instrumentation.

     5. The Scottish Ministers may allow for random measurements to be made instead of continuous measurements for lead, PM2.5 and PM10 by methods for which uncertainty within the 95% confidence interval with respect to continuous monitoring has been demonstrated to be within 10% . Random sampling shall be spread evenly over the year.

Benzene and carbon monoxide
     6. The data quality objectives set out in the following table, for allowed uncertainty of assessment methods, of minimum time coverage and of data capture of measurement are provided to guide quality assurance programmes–

           Benzene Carbon monoxide
Fixed measurements                      
Uncertainty 25% 15%
Minimum data capture 90% 90%
Minimum time coverage 35% urban background and traffic sites (distributed over the year to be representative of various conditions for climate and traffic); 90% industrial sites           
Indicative measurements                      
Uncertainty 30% 25%
Minimum data capture 90% 90%
Minimum time coverage 14% (one day's measurement a week at random, evenly distributed over the year, or eight weeks evenly distributed over the year) 14% (one measurement a week at random, evenly distributed over the year, or eight weeks evenly distributed over the year)
Modelling                      
Uncertainty:                      
Eight-hour averages            50%
Annual averages 50%           
Objective estimation                      
Uncertainty 100% 75%

     7. The uncertainty (on a 95% confidence interval) of the assessment methods shall be evaluated in accordance with the "Guide to the Expression of Uncertainty of Measurements" (ISO 1993) or the methodology of ISO 5725:1994. The percentages for uncertainty in the table in paragraph 6 are given for individual measurements averaged over the period considered by the limit value, for a 95% confidence interval. The uncertainty for the fixed measurements shall be interpreted as being applicable in the region of the appropriate limit value.

     8. The uncertainty for modelling and objective estimation is defined as the maximum deviation of the measured and calculated concentration levels, over the period considered by the limit value, without taking into account the timing of the events.

     9. The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration or the normal maintenance of the instrumentation.

     10. The Scottish Ministers may allow for random measurements to be made instead of continuous measurements for benzene if the uncertainty, including the uncertainty due to random sampling, meets the quality objective of 25% . Random sampling shall be spread evenly over the year.



PART 2

Group B pollutants, polycyclic aromatic hydrocarbons and total gaseous mercury

     11. The data quality objectives set out in the following table are provided to guide quality assurance–

           Benzo(a)pyrene Arsenic, cadmium and nickel Polycyclic aromatic hydrocarbons and total gaseous mercury Total deposition
Uncertainty                                            
Fixed and indicative measurements 50% 40% 50% 70%
Modelling 60% 60% 60% 60%
Minimum data capture 90% 90% 90% 90%
Minimum time coverage                                            
Fixed measurements 33% 50%                      
Indicative measurements(¹) 14% 14% 14% 33%

(¹) Indicative measurement being measurements which are performed at reduced regularity but fulfil the other data quality objectives.

     12. The uncertainty (expressed at a 95% confidence level) of the methods used for the assessment of ambient air concentrations shall be evaluated in accordance with the CEN Guide to the Expression of Uncertainty in Measurement (ENV 13005-1999)[
21], the methodology of ISO 5725:1994, and the guidance provided in the CEN Report, "Air quality – Approach to uncertainty estimation for ambient air reference measurement methods" (CR 14377:2002E). The percentages for uncertainty in the table in paragraph 11 are given for individual measurements, which are averaged over typical sampling times, for a 95% confidence interval. The uncertainty of the measurements shall be interpreted as being applicable in the region of the appropriate target value. Fixed and indicative measurements shall be evenly distributed over the year in order to avoid skewing of results.

     13. The requirements for minimum data capture and time coverage do not include losses of data due to regular calibration or normal maintenance of the instrumentation. Twenty-four-hour sampling is required for the measurement of benzo(a)pyrene and polycyclic aromatic hydrocarbons. With care, individual samples taken over a period of up to one month may be combined and analysed as a composite sample, provided the method ensures that the samples are stable for that period. Where the three congeners benzo(b)fluoranthene, benzo(j)fluoranthene, benzo(k)fluoranthene, are difficult to resolve analytically, they may be reported as sum. The Scottish Ministers shall endeavour, in so far as practicable, to undertake twenty-four hour sampling for the measurement of arsenic, cadmium and nickel concentrations. Sampling shall be spread evenly over the weekdays and the year. For the measurement of deposition rates the Scottish Ministers shall endeavour, in so far as practicable, to obtain monthly, or weekly, samples throughout the year.

     14. The Scottish Ministers may allow for use of wet only instead of bulk sampling if it can be demonstrated to their satisfaction that the difference between them is within 10% . Deposition rates shall generally be given as µg/m³ per day.

     15. The Scottish Ministers may apply a minimum time coverage lower than indicated in the table at paragraph 11, but not lower than 14% for fixed measurements and 6% for indicative measurements provided that they are satisfied that it can be demonstrated that the 95% expanded uncertainty for the annual mean, calculated from the data quality objectives in the table at paragraph 11 according to ISO 11222:2002 – "Determination of the uncertainty of the time average of air quality measurements" will be met.



PART 3

Ozone and related nitrogen oxide and nitrogen dioxide assessed at ozone sampling points

     16. The data quality objectives set out in the following table, for allowed uncertainty of assessment methods, of minimum time coverage and of data capture of measurement, are provided to guide quality-assurance programmes–

           For ozone, NO and NO2 assessed at ozone sampling points
Continuous fixed measurement           
Uncertainty of individual measurements 15%
Minimum data capture 90% during summer; 75% during winter
Indicative measurement           
Uncertainty of individual measurements 30%
Minimum data capture 90%
Minimum time coverage >10% during summer
Modelling           
Uncertainty           
1 hour averages (daytime) 50%
8 hours daily maximum 50%
Objective estimation           
Uncertainty 75%

     17. The uncertainty (on a 95% confidence interval) of the measurement methods shall be evaluated in accordance with the principles laid down in the "Guide to the Expression of Uncertainty of Measurements" (ISO 1993) or the methodology in ISO 5725-1 "Accuracy (trueness and precision) of measurement methods and results" (ISO 1994) or equivalent. The percentages for uncertainty in the table at paragraph 16 are given for individual measurements, averaged over the period for calculating target values and long-term objectives, for a 95% confidence interval. The uncertainty for continuous fixed measurements shall be interpreted as being applicable in the region of the concentration used for the appropriate threshold.

     18. The uncertainty for modelling and objective estimation means the maximum deviation of the measured and calculated concentration levels, over the period for calculating the appropriate threshold, without taking into account the timing of events.

     19. "Time coverage" means the percentage of time considered for settling the threshold value during which the pollutant is measured.

     20. "Data capture" means the ratio of the time for which the instrument produces valid data, to the time for which the statistical parameter or aggregated value is to be calculated.

     21. The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration or normal maintenance of the instrument.



SCHEDULE 9
Regulation 16(3) Regulation 19(4) Regulation 20(4)


Reference methods




PART 1

Group A pollutants

           Reference method
Sampling and measurement of benzene EN 14662:2005, Parts 1, 2 and 3 "Ambient air quality – standard method for measurement of benzene concentrations"[22]
Analysis of carbon monoxide EN 14626:2005 "Ambient air quality – Standard method for the measurement of the concentration of carbon monoxide by nondispersive infrared spectroscopy"
Sampling of lead The same reference method as for PM10
Analysis of lead ISO 9855: 1993 Ambient air – Determination of the particulate lead content of aerosols collected in filters. Atomic absorption spectroscopy method
Analysis of nitrogen dioxide and oxides of nitrogen ISO 7996: 1985 Ambient air – determination of the mass concentrations of nitrogen oxides – chemiluminescence method
Sampling and measurement of PM10 EN 12341:1998 "Air Quality – Field Test Procedure to Demonstrate Reference Equivalence of Sampling Methods for the PM10 fraction of particulate matter". The measurement principle is based on the collection on a filter of the PM10 fraction of ambient particulate matter and the gravimetric mass determination
Analysis of sulphur dioxide ISO/FDIS 10498 (Standard in draft) Ambient air – determination of sulphur dioxide – ultraviolet fluorescence method



PART 2

Group B pollutants in ambient air

           Reference method
Sampling of Group B pollutants other than benzo(a)pyrene The same method as for sampling and measurement of PM10
Analysis of Group B pollutants other than benzo(a)pyrene EN 14902:2005 "Ambient air quality – standard method for the measurement of Pb, Cd, As and NI in the PM10 fraction of suspended particulate matter"
Benzo(a)pyrene concentrations A method based on manual PM10 sampling equivalent to EN 12341



PART 3

Ozone

           Reference method
Measurement of ozone EN 14625:2005 "Ambient air quality – standard method for the measurement of the concentration of ozone by ultraviolet photometry"



PART 4

Other reference methods

           Reference method
Sampling and analysis of polycyclic aromatic hydrocarbons in ambient air A method based on manual PM10 sampling equivalent to EN 12341
Sampling and analysis of mercury in ambient air An automated method based on Atomic Absorption Spectrometry or Atomic Fluorescence Spectrometry
Sampling and analysis of the deposition of Group B pollutants, mercury, and polycyclic aromatic hydrocarbons A method based on the exposition of cylindrical deposit gauges with standardised dimensions



SCHEDULE 10
Regulation 18


Ozone precursor substances


Objectives
     1. The main objectives of measurements of ozone precursor substances are to analyse any trend in ozone precursors, to check the efficiency of emission reduction strategies, to check the consistency of emission inventories and to help attribute emission sources to pollution concentration.

     2. An additional aim is to support the understanding of ozone formation and precursor dispersion processes, as well as the application of photochemical models.

Substances
     3. Measurements of ozone precursor substances shall include at least nitrogen oxides, and appropriate volatile organic compounds. For the purposes of this Schedule, "volatile organic compounds" means all organic compounds from anthropogenic and biogenic sources, other than methane, that are capable of producing photochemical oxidants by reaction with nitrogen oxides in the presence of sunlight.

     4. The Scottish Ministers shall, in particular, consider measuring the following volatile organic compounds–

Ethane 1-Butene Isoprene Ethyl benzene
Ethylene trans-2-Butene n-Hexane m+p-Xylene
Acetylene cis-2-Butene i-Hexane o-Xylene
Propane 1.3-Butadiene n-Heptane 1,2,4-Trimeth. benzene
Propene n-Pentane n-Octane 1,2,3-Trimeth. benzene
n-Butane i-Pentane i-Octane 1,3,5-Trimeth. benzene
i-Butane 1-Pentene Benzene Formaldehyde
           2-Pentene Toluene Total non-methane hydrocarbons

Reference methods
     5. The reference method for the analysis of oxides of nitrogen shall be ISO 7996:1985, Ambient air – determination of the mass concentrations of nitrogen oxides – chemiluminescence method.

Monitoring sites
     6. Measurements shall be taken in particular in urban and suburban areas at any monitoring site considered appropriate with regard to the objectives set out in this Schedule.



SCHEDULE 11
Regulation 24(1)


Public information where alert or information thresholds are exceeded




PART 1

Alert thresholds for nitrogen dioxide and sulphur dioxide

     1. In cases where the alert thresholds for nitrogen dioxide or sulphur dioxide are exceeded, the information to be made available to the public shall include at least–



PART 2

Alert and information thresholds for ozone

     2. In cases where either the information threshold or the alert threshold for ozone–

the details set out in paragraphs 3 to 6 shall, as a minimum, be made available to the public on a sufficiently large scale.

     3. Information on any observed exceedance–

     4. Forecast for the following afternoon, day or days–

     5. Information on the type of population concerned, possible health effects and recommended conduct, in particular–

     6. Information provided under this Schedule shall also include–



SCHEDULE 12
Regulations 26(2)(a) & 29


Collation of information and criteria for aggregating data and calculating statistical parameters




PART 1

Information to be submitted to the Commission

     1. The following information on ozone concentrations shall be obtained and collated–

           Type of station Level Averaging/accumulation time Provisional data for each month from April to September Report for each year
Information threshold Any 180µg/m³ 1 hour For each day with any exceedance: date, total hours of, exceedance, maximum 1 hour ozone and related NO2 values when required and monthly 1 hour maximum ozone For each day with any exceedance: date, total hours of exceedance, maximum 1 hour ozone and related NO2 values, when required
Alert threshold Any 240µg/m³ 1 hour For each day with any exceedance: date, total hours of exceedance, maximum 1 hour ozone and related NO2 values, when required For each day with any exceedance: date, total hours of exceedance, maximum 1 hour ozone and related NO2 values, when required
Health protection Any 120µg/m³ 8 hours For each day with any exceedance: date, 8 hours maximum(¹) For each day with any exceedance: date, 8 hours maximum(¹)
Vegetation protection Suburban, rural, rural background AOT40(²) = 6,000 µg/m³.h 1 hour, accumulated from May to June            Value
Forest protection Suburban, rural, rural background AOT40(²) = 20,000µg/m³.h 1 hour, accumulated from April to September            Value
Materials Any 40 µg/m³ 1 year            Value

(¹) Maximum daily 8-hour mean.

(²) In this table, "AOT40" has the same meaning as in paragraph 3(d) of Part 4 of Schedule 1.

     2. The Scottish Ministers shall also ensure that the following information is collated–

     3. Data collated in monthly reports shall be considered provisional and shall be updated where necessary in subsequent submissions.



PART 2

Criteria for aggregating data and calculating statistical parameters

     4. In this Part, percentiles are to be calculated using the method specified in Council Decision 97/101/EC[
23] establishing a reciprocal exchange of information and data from networks and individual stations measuring ambient air pollution within member States.

     5. The following criteria are to be used for checking validity when aggregating data and calculating statistical parameters–

Parameter Required proportion of valid data
1 hour values 75% (45 minutes)
8 hour values 75% of values (6 hours)
Maximum daily 8 hours mean from hourly running 8 hours averages 75% of the hourly running 8 hour averages (18 8 hours averages per day)
AOT40(¹) 90% of the 1 hour values over the time period defined for calculating the AOT40 value(²)
Annual mean 75% of the 1 hour values over summer (April to September) and winter (January to March, October to December) seasons separately
Number of exceedances and maximum values per month 90% of the daily maximum 8 hours mean value (27 available daily values per month)

90% of the 1 hour values between 08:00 and 20:00 Central European Time

Number of exceedances and maximum values per year Five out of six summer months over the summer season (April to September)

(¹) In this table "AOT40" has the same meaning as in paragraph 3(d) of Part 4 of Schedule 1.

(²) In cases where all possible measured data are not available, the following factor shall be used to calculate AOT40 values: AOT40 (estimate) = AOT40 measured x (total possible number of hours ÷ number of measured hourly values). The reference in this formula to the total possible number of hours is to the hours within the time period of AOT40 definition (that is, 08:00 to 20:00 Central European Time from 1st May to 31st July each year, for vegetation protection and from 1st April to 30th September each year for forest protection).



EXPLANATORY NOTE

(This note is not part of the Regulations)


These Regulations extend to Scotland only.

These Regulations implement the following Directives:

These Regulations also incorporate requirements imposed by the following:

In addition to providing for the transposition of the Fourth Daughter Directive, these Regulations consolidate and replace the Air Quality Limit Values (Scotland) Regulations 2003 (S.S.I. 2003/428) (as amended by the Air Quality Limit Values (Scotland) Amendment Regulations 2003 (S.S.I. 2003/547) and the Air Quality Limit Values (Scotland) Amendment Regulations 2005 (S.S.I. 2005/300)), all of which are revoked by regulation 30. Those Regulations previously implemented for Scotland the air quality Directives referred to above except the Fourth Daughter Directive.

Regulation 3 designates the Scottish Ministers as the competent authority for the purposes of Article 3 (implementation and responsibilities) of Council Directive 96/62/EC.

Chapter 1 of Part 2 of these Regulations requires the attainment of air quality standards in respect of the concentration of various pollutants in ambient air. In accordance with regulation 6 and Schedule 1, limit values are imposed for "Group A" pollutants (benzene, carbon monoxide, lead, nitrogen dioxide and oxides of nitrogen, particulate matter (PM10) and sulphur dioxide); target values are imposed for "Group B" pollutants (arsenic, benzo(a)pyrene, cadmium and nickel, and their compounds) within the PM10 fraction; and target values and long-term objectives are imposed for ozone. For the purposes of this Part, regulation 5 requires the Scottish Ministers to divide Scotland into zones within which the necessary air quality management and assessment takes place.

Chapter 2 of Part 2 sets out the measures the Scottish Ministers are required to take in order to ensure attainment of the relevant standards. The measures ordinarily required are those set out in regulation 7. In relation to benzene or nitrogen dioxide, where concentrations exceed the limit value plus the margin of tolerance specified, the Scottish Ministers are required by regulation 8(2) to prepare and implement an improvement plan. The Scottish Ministers are also required to prepare and implement an improvement plan by regulation 8(3) in cases where concentrations of ozone exceed the target value, unless the Scottish Ministers consider that the target value would not be attainable through proportionate measures. Schedule 2 makes provision as to the content of improvement plans. Regulation 9 requires the Scottish Ministers to take the measures specified in cases where concentrations of Group B pollutants exceed the relevant target value or in cases where concentrations of ozone comply with the target value but exceed a long-term objective.

Regulation 10 requires the Scottish Ministers to maintain compliance with the limit values and target values and, as far as the factors specified in that regulation permit, the long-term objectives for ozone. Regulation 11 requires the Scottish Ministers to prepare and, to the extent they consider necessary, implement, action plans which indicate the measures to be taken in cases where there is a risk that any limit value or the alert thresholds for nitrogen dioxide and sulphur dioxide will be exceeded. The Scottish Ministers are also obliged to consider the preparation of action plans where there is a risk that the alert threshold for ozone will be exceeded. Alert thresholds are set out in Schedule 3.

Regulation 12 requires the Scottish Ministers to assess the concentration of Group A pollutants, Group B pollutants and ozone within each zone. Regulations 13 to 16 and Schedules 4 to 9 prescribe the assessment methods which are required or permitted (as the case may be), and the detailed requirements in relation to each method (for instance, requirements as to sampling points for fixed measurement).

Regulations 17 to 19 require the Scottish Ministers to monitor or measure, respectively, PM2.5, ozone precursor substances and certain polycyclic aromatic hydrocarbons. Schedule 10 makes specific provision for the measurement of ozone precursor substances. Regulation 20 requires the taking of indicative measurements of the concentration and deposition of Group B pollutants, basic polycyclic aromatic hydrocarbons and mercury.

Regulations 21 to 25 and Schedule 11 require the Scottish Ministers to make up-to-date information available to the public, including organisations representing relevant public interests. Regulation 26 requires the production of an annual report for ozone and regulation 27 requires action and improvement plans, and information as to their implementation, to be made available. Regulation 28 requires the Scottish Ministers to consult the public in the preparation, modification and review of improvement plans. Regulation 29 requires the Scottish Ministers to obtain and collate certain information contained in Schedule 12.


Notes:

[1] 1972 c. 68. Section 2(2) was amended by the Scotland Act 1998 (c.46), Schedule 8 paragraph 15(3). The function of the Minister of the Crown exercisable under section 2(2) was, in so far as exercisable within devolved competence, transferred to the Scottish Ministers by section 53 of the Scotland Act 1998.back

[2] This standard is issued by the European Committee for Standardisation (CEN); (copies may be obtained from CEN at 36, Rue de Stassart B-1050, Brussels, Belgium, http://www.cenorm.be).back

[3] O.J. No L 296, 21.11.96, p.55.back

[4] O.J. No L 163, 29.06.99, p.41.back

[5] O.J. No L 313, 13.12.00, p.12.back

[6] O.J. No L 67, 09.03.02, p.14.back

[7] O.J. No L 23, 26.01.05, p.3.back

[8] O.J. No L 257, 10.10.96, p.26.back

[9] The Directive is implemented by the Pollution Prevention and Control (Scotland) Regulations 2000 (S.S.I. 2000/323 as amended by the Antisocial Behaviour etc. (Scotland) Act 2004 (asp 8), Schedule 2 paragraph 7, S.S.I. 2002/493, S.S.I. 2003/146, 170, 221 and 235, S.S.I. 2004/26, 110, 112 and 512, S.S.I. 2005/101, 340 and 510).back

[10] O.J. No. L 87, 25.03.04, p.50.back

[11] S.S.I. 2003/428 amended by S.S.I. 2003/547 and S.S.I. 2005/300.back

[12] The European co operative programme for Monitoring and Evaluation of the long-range transmission of air pollutants in Europe (http://www.emep.int).back

[13] S.S.I. 2003/428.back

[14] S.S.I. 2003/547.back

[15] S.S.I. 2005/300.back

[16] Regulation 6 of S.I. 1989/317 has been revoked so far as it applies in Scotland by S.S.I. 2003/428 (regulation 16) but with effect from 1st January 2010, so that this revocation will not have taken effect by the time S.S.I. 2003/428 is itself revoked.back

[17] S.I. 1989/317, amended by S.I. 1995/3146 in relation to regulation 6.back

[18] S.I. 1995/3146.back

[19] O.J. No L 125, 18.05.94, p.1.back

[20] Copies of International Standards Organisation publications referred to in this Schedule or in Schedule 9 may be purchased from the British Standards Institution ("BSI") Sales Department either by telephone (0208 996 9001) or by post from the BSI, Standards House, 389 Chiswick High Road, London W4 4AL, http://www.bsi-global.com.back

[21] European Committee for Standardisation (CEN) publication; (copies may be obtained from CEN at 36, Rue de Stassart, B 1050, Brussels, Belgium, http://www.cenorm.be).back

[22] This standard is issued by the European Committee for Standardisation (CEN); (copies may be obtained from CEN at 36, Rue Stassart B-1050, Brussels, Belgium, http://www.cenorm.be).back

[23] O.J. L 35, 05.02.97, p.14.back



ISBN 978 0 11 072017 3


 © Crown copyright 2007

Prepared 21 March 2007


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